Morphological stability of three-dimensional cementite rods in polycrystalline system: A phase-field analysis
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Transformations accompanying shape-instability govern the morphological configuration and distribution of the phases in a microstructure. Owing to the influence of the microstructure on the properties of a material, the stability of three-dimensional rods in a representative polycrystalline system is extensively analysed. A multiphase-field model, which recovers the physical laws and sharp-interface relations, and includes grain boundary diffusion, is adopted to investigate the morphological evolution of the precipitate. Moreover, the efficiency of the numerical approach is ensured by establishing the volume-preserving chemical equilibrium through the incorporation TCFe8 (CALPHAD) data and solving phase-field evolution in the Allen-Cahn framework. The morphological evolution of the rod in the multiphase system exhibits a unique transformation mechanism which is significantly different from the evolution of an isolated finite-structure. It is realised that, in a polycrystalline arrangement, irrespective of the initial rod-size , the shape-change begins with the energy-minimising events at the triple junctions. This early transformation renders a characteristic morphology at the longitudinal ends of the structure, which introduces sufficient driving-force through the curvature-difference for the subsequent morphological changes. The continued mass transfer to the terminations, ultimately, breaks-off the rod into separate entities that are entangled in the grain boundary. With increasing aspect ratio of the rod, it is identified that the source of mass transfer, which turns into the ovulation site, shifts from the centre. This increases the number of fragmentation events and introduces satellite particle. A comprehensive understanding of the transformation kinetics and mechanism governing the morphological evolution of the rods in a polycrystalline system is rendered in this work.
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